Fusion and planarization of a quinoidal porphyrin dimer

被引：61

作者：

Blake, IM ^{[1
]}

Krivokapic, A ^{[1
]}

Katterle, M ^{[1
]}

Anderson, HL ^{[1
]}

机构：

[1] Univ Oxford, Dyson Perrins Lab, Dept Chem, Oxford OX1 3QY, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 16期

关键词：

D O I：

10.1039/b204265g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure, near-infrared spectrum and electrochemistry of a quinoidal triply-linked porphyrin dimer are compared with those of its singly-linked precursor; fusing the two porphyrins planarizes the pi-system and reduces the optical HOMO-LUMO gap while increasing the gap between the first oxidation and reduction potentials.

引用

页码：1662 / 1663

页数：2

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