Cobalt-catalyzed selective conversion of diallylanilines and arylimines to quinolines

被引：18

作者：

Jacob, J

Cavalier, CM

Jones, WD ^{[1
]}

Godleski, SA

Valente, RR

机构：

[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

[2] Eastman Kodak Co, Rochester, NY 14650 USA

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2002年 / 182卷 / 01期

基金：

美国国家科学基金会;

关键词：

quinolines; cobalt; C-N cleavage; catalysis; heterocycles;

D O I：

10.1016/S1381-1169(01)00493-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dicobaltoctacarbonyl has been found to bean effective catalyst for the conversion of diallylanilines to quinolines. Arylimines are also found to undergo heteroannulation in the presence of diallylaniline as allyl fragment donor to give quinolines. Imines can also be allylated to give quinoline derivatives. Initial studies of the scope and mechanism of the reaction are presented. (C) 2002 Elsevier Science B.V. All rights reserved.

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收藏

页码：565 / 570

页数：6

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