Synthesis and electroluminescent properties of bis(3-N-ethylcarbazolyl)cyanoterephthalidene

被引:30
作者
Park, JW [1 ]
Lee, JH
Lee, HS
Kang, DY
Kim, TW
机构
[1] Chungju Natl Univ, Dept Polymer Engn, Chungju 380702, South Korea
[2] Samsung Display Devices, Flat Display Lab, Suwon 442391, South Korea
[3] Hongik Univ, Dept Elect Engn, Seoul 121791, South Korea
[4] Hongik Univ, Dept Phys, Seoul 121791, South Korea
基金
新加坡国家研究基金会;
关键词
electroluminescence; bis(3-N-ethylcarbazolyl)cyanoterephthalidene (BECCP); poly(3,6-N-2-ethylhexylcarbazolyl cyanotere-phthalidene (PECCP); blue emitting material;
D O I
10.1016/S0040-6090(99)01008-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A new blue electroluminescent material analog to poly(3,6-N-2-ethplhexylcarbazolyl cyanotere-phthalidene) (PECCP) was synthesized by a facile reaction of 9-ethyl-3 -carbazole carboxy aldehyde with 1,4-phenylenediacetonitrile. The re suiting bis(3-N-ethylcarbazolyl)cyanoterephthalidene (BECCP) having cyano (electron acceptor part) and carbazole moiety (electron donor part) was characterized by NMR, IR, UV and was vacuum-deposited into thin film of smooth surface. BECCP shows blue PL and EL spectra at 480 nm corresponding to 2.58 eV and typical rectifying diode characteristics in ITO/BECCP/Al devices in both forward and reverse bias. The turn on voltage are +8 V and 4 V when the BECCP layer are 600 and 300 Angstrom thick, respectively. (C) 2000 Elsevier Science S.A, Ail rights reserved.
引用
收藏
页码:90 / 93
页数:4
相关论文
共 8 条
[1]   LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].
BURROUGHES, JH ;
BRADLEY, DDC ;
BROWN, AR ;
MARKS, RN ;
MACKAY, K ;
FRIEND, RH ;
BURN, PL ;
HOLMES, AB .
NATURE, 1990, 347 (6293) :539-541
[2]  
CHO SW, 1999, IN PRESS J SID
[3]   A novel series of p-n diblock light-emitting copolymers based on oligothiophenes and 1,4-bis(oxadiazolyl)-2,5-dialkyloxybenzene [J].
Huang, W ;
Meng, H ;
Yu, WL ;
Pei, J ;
Chen, ZK ;
Lai, YH .
MACROMOLECULES, 1999, 32 (01) :118-126
[4]   Tunable electroluminescence from silicon-containing poly(p-phenylenevinylene)-related copolymers with well-defined structures [J].
Kim, HK ;
Ryu, MK ;
Kim, KD ;
Lee, SM ;
Cho, SW ;
Park, JW .
MACROMOLECULES, 1998, 31 (04) :1114-1123
[5]  
PARK JW, 1995, POLYM PREPR AM CHEM, V36, P259
[6]   Electroluminescence of 1,3,4-oxadiazole and triphenylamine-containing molecules as an emitter in organic multilayer light emitting diodes [J].
Tamoto, N ;
Adachi, C ;
Nagai, K .
CHEMISTRY OF MATERIALS, 1997, 9 (05) :1077-1085
[7]   ORGANIC ELECTROLUMINESCENT DIODES [J].
TANG, CW ;
VANSLYKE, SA .
APPLIED PHYSICS LETTERS, 1987, 51 (12) :913-915
[8]   Synthesis and characterization of a new p-n diblock light-emitting copolymer [J].
Yu, WL ;
Meng, H ;
Pei, J ;
Huang, W ;
Li, YF ;
Heeger, AJ .
MACROMOLECULES, 1998, 31 (15) :4838-4844