A staudinger approach towards binol-derived MAP-type bidentate PN ligands

被引：33

作者：

Botman, PNM ^{[1
]}

David, O ^{[1
]}

Amore, A ^{[1
]}

Dinkelaar, J ^{[1
]}

Vlaar, MT ^{[1
]}

Goubitz, K ^{[1
]}

Fraanje, J ^{[1
]}

Schenk, H ^{[1
]}

Hiemstra, I ^{[1
]}

van Maarseveen, JH ^{[1
]}

机构：

[1] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1018 WS Amsterdam, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 26期

关键词：

azides; biaryl compounds; nucleophilic aromatic substitution; P ligands;

D O I：

10.1002/anie.200454146

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An intramolecular SNAr reaction makes the synthesis of enantiopure MAP(O)-type P,N ligands in high yields possible (see scheme) and demonstrates that the synthetic potential of the 85-year-old Staudinger reaction between phosphanes and azides is still far from being exhausted. Nf = nonafluorobutanesulfonate.

引用

页码：3471 / 3473

页数：3

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