Vanadium complexes: Recent progress in oxidation catalysis

被引：227

作者：

Sutradhar, Manas ^{[1
]}

Martins, Luisa M. D. R. S. ^{[1
,2
]}

da Silva, M. Fatima C. Guedes ^{[1
]}

Pombeiro, Armando J. L. ^{[1
]}

机构：

[1] Univ Lisbon, Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal

[2] ISEL, Dept Chem Engn, P-1959007 Lisbon, Portugal

来源：

COORDINATION CHEMISTRY REVIEWS | 2015年 / 301卷

关键词：

Oxidovanadium complexes; Oxidation of alkanes; Oxidation of alcohols; Epoxidation; Sulfoxidation; Homogeneous and supported catalysis; SCHIFF-BASE LIGANDS; MONONUCLEAR OXIDOVANADIUM(V) COMPLEX; 1,3-DITHIANE 1-OXIDE AUXILIARY; SINGLE-POT HYDROCARBOXYLATION; APROTIC CONJUGATE ADDITION; OXYGEN-TRANSFER REACTIONS; L-CYSTEINE SULFOXIDE; BEARING POLAR GROUPS; C-H; ASYMMETRIC EPOXIDATION;

D O I：

10.1016/j.ccr.2015.01.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxidovanadium complexes and, to a less extent, some non-oxido ones, are widely used as catalysts or catalyst precursors for various oxidative catalytic reactions by H2O2, (BuOOH)-Bu-t or O-2 under mild conditions. Oxidation reactions (oxidation of alkanes and alcohols, epoxidation of alkenes and allylic alcohols, oxidative bromination, sulfoxidation and oxidative Strecker reactions) of organic compounds are the most relevant ones and are reviewed considering the recent advances in the last five years (2010-2014). The main types of both homogeneous and supported vanadium catalysts and the most efficient catalytic systems in the different reactions are presented and compared. The proposed mechanisms of various catalytic oxidation processes are also outlined. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：200 / 239

页数：40

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