Physicochemical characterization of the decomposition course of hydrated holmium nitrate. Thermoanalytical studies

Ho(NO3)(3). 5H(2)O (HoNit) was used as a parent compound for the formation of Ho2O3 at up to 800 degrees C in atmosphere of air. Thermal processes occurring during the decomposition course were monitored by means of differential thermal analysis (DTA), thermogravimetry (TG) and gas-mass spectroscopy. The intermediates and final solid products were characterized by infrared (IR) spectroscopy, X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The results showed that, HoNit decomposes completely through eight endothermic weight losses processes. The dehydration occurs through the first four steps at 120 degrees, 140 degrees, 205 degrees and 240 degrees, forming crystalline nitrate monohydrate, which decomposes to Ho(OH)(NO,), at 265 degrees C. The latter, decomposes immediately to form a stable and crystalline HoO(NO3) at 368 degrees C, then to nonstoichiometric unstable intermediates; Ho(O)(1.25)(NO3)(0.5) at 500 degrees C. Finally, Ho2O3 was formed at 560 degrees C. The decomposition course and surface morphology were supported and followed by SEM. The final product Ho2O3 at 600 degrees C has large crystalline with irregular sheet-shaped particles containing large pores, voids and cracks. The gaseous decomposition products as identified by gas-mass spectroscopy are water vapor, nitric acid and nitrogen oxides (NO, NO2 and N2O5). (C) 2000 Elsevier Science S.A. All rights reserved.