(PCy3)2Cl2Ru=CHPh Catalyzed Kharasch additions.: Application in a formal olefin carbonylation

被引：55

作者：

Lee, BT ^{[1
]}

Schrader, TO ^{[1
]}

Martín-Matute, B ^{[1
]}

Kauffman, CR ^{[1
]}

Zhang, P ^{[1
]}

Snapper, ML ^{[1
]}

机构：

[1] Boston Coll, Eugene F Merkert Chem Ctr, Dept Chem, Chestnut Hill, MA 02467 USA

来源：

TETRAHEDRON | 2004年 / 60卷 / 34期

关键词：

Kharasch; metathesis; radical; carbonylation;

D O I：

10.1016/j.tet.2004.06.066

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(PCy3)(2)Cl2Ru=CHPh-catalyzed Kharasch additions of trihaloalkanes across olefins provide polyhalogenated adducts, which upon hydrolysis furnish alpha,beta-unsaturated ketones, aldehydes, or gamma-hydroxybutenolides. This two-step process represents an overall acylation or carbonylation of an olefin. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：7391 / 7396

页数：6

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