An enzyme mimic that hydrolyzes an unactivated ester with catalytic turnover

被引:45
作者
Yan, JM [1 ]
Breslow, R [1 ]
机构
[1] Columbia Univ, Dept Chem, New York, NY 10027 USA
基金
美国国家卫生研究院;
关键词
cyclodextrin dimer; copper;
D O I
10.1016/S0040-4039(00)00114-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The Cu(II) complex of a cyclodextrin dimer linked by a bipyridyl unit catalyzes the hydrolysis of an unactivated doubly-bound benzyl ester. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2059 / 2062
页数:4
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