A direct borohydride -: Acid peroxide fuel cell

被引:128
作者
de Leon, C. Ponce
Walsh, F. C. [1 ]
Rose, A.
Lakeman, J. B.
Browning, D. J.
Reeve, R. W.
机构
[1] Univ Southampton, Sch Engn Sci, Electrochem Engn Grp, Southampton SO17 1BJ, Hants, England
[2] Dept Phys Sci, Salisbury SP4 0QR, Wilts, England
关键词
borohydride ion; carbon felt; filter-press cell; FM01-LC cell; hydrogen peroxide; liquid fuel cell;
D O I
10.1016/j.jpowsour.2006.10.069
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A fuel cell operating with aqueous sodium borohydride and hydrogen peroxide streams, with one, two and four cells (electrode area 64, 128 and 256 cm(2)) connected in a bipolar mode in a filterpress flow cell is reported. The oxidation of borohydride ion was carried out on Au/C particles supported on a carbon felt electrode while the reduction of hydrogen peroxide was carried out on carbon supported Pt on a carbon paper substrate. Comparable cell potentials and power densities to direct borohydride fuel cells reported in the literature were obtained. The challenges to further development includes: increasing the low current density and avoid decomposition of borohydride and peroxide ions. The maximum power obtained at 20 degrees C for One, two and four cell stacks was 2.2, 3.2 and 9.6 W (34.4, 25 and 37.5 mW cm(-2), respectively) with cell voltages of 1.06, 0.81 and 3.2 V at current densities of 32, 16 and 12 mA cm(-2), respectively. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:441 / 448
页数:8
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