Thermal stability of mesoporous boron nitride templated with a cationic surfactant

被引：46

作者：

Dibandjo, P. ^{[1
]}

Bois, L. ^{[1
]}

Chassagneux, F. ^{[1
]}

Miele, P. ^{[1
]}

机构：

[1] Univ Lyon 1, UMR 5615, Lab Multimat & Interfaces, Villeurbanne, France

来源：

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2007年 / 27卷 / 01期

关键词：

nitrides; porosity; surfactant; BN;

D O I：

10.1016/j.jeurceramsoc.2006.04.178

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The preparation of mesoporous boron nitride by using tris(monomethylamino)borazine (MAB) as boron nitride source and cetyltrimethylammonium bromide (CTAB) as structurating agent is reported. The X-ray diffraction, TEM and pore size analysis show that highly porous boron nitride (specific surface area of 800 m(2)/g and mesoporous volume of 0.5 cm(3)/g) is synthesized with mesopores of 6 nm in diameter. Moreover, the mesoporosity is conserved up to 1600 degrees C under an inert atmosphere. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：313 / 317

页数：5

共 39 条

[1] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].

BECK, JS ;

VARTULI, JC ;

ROTH, WJ ;

LEONOWICZ, ME ;

KRESGE, CT ;

SCHMITT, KD ;

CHU, CTW ;

OLSON, DH ;

SHEPPARD, EW ;

MCCULLEN, SB ;

HIGGINS, JB ;

SCHLENKER, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843

[2] Pyrolysis of poly[2,4,6-tri(methylamino)borazine] and its conversion into BN fibers [J].

Bernard, S ;

Cornu, D ;

Miele, P ;

Vincent, H ;

Bouix, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 657 (1-2) :91-97

[3]

Blum R, 2003, MATER RES SOC SYMP P, V775, P71

[4] B-TRICHLOROBORAZOLE [J].

BROWN, CA ;

LAUBENGAYER, AW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (14) :3699-3700

[5] Porosity control in pre-ceramic molecular precursor-derived GaN based materials [J].

Chaplais, G ;

Kaskel, S .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (06) :1017-1025

[6] Preparation of a mesoporous silicon aluminium nitride via a non-aqueous sol-gel route [J].

Cheng, F ;

Kelly, SM ;

Lefebvre, F ;

Clark, S ;

Supplit, R ;

Bradley, JS .

JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (07) :772-777

[7] Boron nitride nanomesh [J].

Corso, M ;

Auwärter, W ;

Muntwiler, M ;

Tamai, A ;

Greber, T ;

Osterwalder, J .

SCIENCE, 2004, 303 (5655) :217-220

[8] Thermal stability of mesoporous silica molecular sieve [J].

Cu, G ;

Ong, PP ;

Chu, C .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1999, 60 (07) :943-947

[9] Pore structure and graphitic surface nature of ordered mesoporous carbons probed by low-pressure nitrogen adsorption [J].

Darmstadt, H ;

Roy, C ;

Kaliaguine, S ;

Joo, SH ;

Ryoo, R .

MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 60 (1-3) :139-149

[10] Comparison between SBA-15 silica and CMK-3 carbon nanocasting for mesoporous boron nitride synthesis [J].

Dibandjo, P ;

Chassagneux, F ;

Bois, L ;

Sigala, C ;

Miele, P .

JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (19) :1917-1923

← 1 2 3 4 →