Preparation and crystal structure of a dimolybdenum(II) complex with the drug ibuprofen

被引：13

作者：

Cotton, FA ^{[1
]}

Silva, DDO ^{[1
]}

机构：

[1] TEXAS A&M UNIV,MOL STRUCT & BONDING LAB,COLLEGE STN,TX 77843

来源：

INORGANICA CHIMICA ACTA | 1996年 / 249卷 / 01期

关键词：

dimolybdenum compounds; ibuprofen; crystal structures;

D O I：

10.1016/0020-1693(96)05181-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of dimolybdenum(II) complexes with the drug ibuprofen has been investigated. The compound [Mo-2(R-C13H17O2)(2-) (S-C13H17O2)(2)] has been structurally characterized. It crystallizes in the monoclinic space group P2(1)/c, with unit cell dimensions a = 5.5307(6), b = 30.634(5), c = 15.234(2) Angstrom, beta = 91.87(8)degrees, V = 2579.8(6) Angstrom(3), Z = 2. The asymmetric unit consists of half of the molecule which resides on a crystallographic inversion center. The configurations of the four chiral ligands around the dimetal unit follow the cyclic order RRSS. The Mo-Mo distance is 2.085(2) Angstrom.

引用

页码：57 / 61

页数：5

共 20 条

[1]

AKHMEDOV EL, 1980, ZH NEORG KHIM+, V25, P3305

[2] COMPLEXES OF DIMOLYBDENUM(II) WITH DL-AMINO ACIDS .2. CRYSTAL-STRUCTURE OF COMPOUNDS CONTAINING DL-VALINE AND DL-LEUCINE [J].

APFELBAUM, F ;

BINO, A .

INORGANICA CHIMICA ACTA, 1989, 155 (02) :191-195

[3] COMPLEXES OF DIMOLYBDENUM(II) WITH DL-AMINO ACIDS [J].

APFELBAUMTIBIKA, F ;

BINO, A .

INORGANIC CHEMISTRY, 1984, 23 (18) :2902-2905

[4] CRYSTAL-STRUCTURE AND POLARIZED, LOW-TEMPERATURE ELECTRONIC ABSORPTION-SPECTRUM OF "TETRAKIS(L-LEUCINE)DIMOLYBDENUM(II) DICHLORIDE BIS(PARA-TOLUENESULFONATE) DIHYDRATE [J].

BINO, A ;

COTTON, FA ;

FANWICK, PE .

INORGANIC CHEMISTRY, 1980, 19 (05) :1215-1221

[5] IDENTIFICATION AND STRUCTURAL CHARACTERIZATION OF [ENH2]2[MO2CL8].2H2O, A COMPOUND CONTAINING OCTACHLORODIMOLYBDATE(II) ION [J].

BRENCIC, JV ;

COTTON, FA .

INORGANIC CHEMISTRY, 1969, 8 (12) :2698-&

[6] PREPARATION OF SOME COMPOUNDS CONTAINING MULTIPLE MOLYBDENUM-MOLYBDENUM BONDS [J].

BRENCIC, JV ;

COTTON, FA .

INORGANIC CHEMISTRY, 1970, 9 (02) :351-&

[7]

BRUGGEMANN R, 1992, Z KRISTALLOGR, V5, P33

[8]

Cotton F. A., 1993, MULTIPLE BONDS METAL

[9] PREPARATION AND STRUCTURE OF CRYSTALLINE TETRAKIS(D-MANDELATO)DIMOLYBDENUM(II) BIS(TETRAHYDROFURANATE) [J].

COTTON, FA ;

FALVELLO, LR ;

MURILLO, CA .

INORGANIC CHEMISTRY, 1983, 22 (03) :382-387

[10]

COTTON FA, 1995, INORG CHIM ACTA, V234, P115

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