Sb2MoO6, a re-examination

被引：21

作者：

Castro, A ^{[1
]}

Enjalbert, R ^{[1
]}

Galy, J ^{[1
]}

机构：

[1] CSIC,INST CIENCIA MAT MADRID,E-28049 MADRID,SPAIN

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷

关键词：

D O I：

10.1107/S0108270197006239

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single crystals of diantimony molybdenum hexaoxide have been grown by solid-state reaction. This oxide crystallizes as a layered structure, as in the case of the previously reported Sb2WO6. Mo atoms are located in severely distorted O-atom octahedra while each Sb atom is bonded to five O atoms, three at short distances and two at longer distances, retaining the three-dimensional array.

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页码：1526 / 1529

页数：4

相关论文

共 16 条

[1] STRUCTURAL REFINEMENT OF THE HIGH-TEMPERATURE FORM OF BI2MOO6 [J].

BUTTREY, DJ ;

VOGT, T ;

WILDGRUBER, U ;

ROBINSON, WR .

JOURNAL OF SOLID STATE CHEMISTRY, 1994, 111 (01) :118-127

[2] AN ORIGINAL OXIDE OF ANTIMONY AND TUNGSTEN RELATED TO AURIVILLIUS PHASES [J].

CASTRO, A ;

MILLAN, P ;

ENJALBERT, R ;

SNOECK, E ;

GALY, J .

MATERIALS RESEARCH BULLETIN, 1994, 29 (08) :871-879

[3] STRUCTURAL EVOLUTION OF THE AURIVILLIUS FRAMEWORK IN THE SOLID-SOLUTIONS BI2WO6-SB2WO6 [J].

CASTRO, A ;

MILLAN, P ;

ENJALBERT, R .

MATERIALS RESEARCH BULLETIN, 1995, 30 (07) :871-882

[4] SUBSTITUTIONS FOR BI-3+ INTO (BI2O2)2+ LAYERS OF THE AURIVILLIUS (BI2O2) (AN-1BNO3N+1) OXIDES [J].

CASTRO, A ;

MILLAN, P ;

MARTINEZLOPE, MJ ;

TORRANCE, JB .

SOLID STATE IONICS, 1993, 63-5 :897-901

[5]

ELZEN AF, 1973, ACTA CRYSTALLOGR B, V29, P2436

[6]

*ENR, 1994, CAD 4 EXPRESS VERS 5

[7] STEREOCHEMISTRY OF ELEMENTS WHICH ARE UNBOUND PAIRS - GE (II), AS (III), SE (IV), BR (V), SN (II), SB (III), TE (IV), I (V), XE (VI), TL (I), PB (II), AND BI (III) (OXIDES, FLUORIDES AND OXYFLUORIDES) [J].

GALY, J ;

MEUNIER, G ;

ANDERSSON, S ;

ASTROM, A .

JOURNAL OF SOLID STATE CHEMISTRY, 1975, 13 (1-2) :142-159

[8]

Johnson C. K., 1976, ORNL5138

[9] CRYSTAL-STRUCTURE OF SB2MOO6 [J].

LAARIF, A ;

THEOBALD, FR ;

VIVIER, H ;

HEWAT, AW .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1984, 167 (1-2) :117-124

[10] Antiferroelectric modulations in Sb2WO6 and Sb2MoO6 [J].

Ling, CD ;

Withers, RL ;

Rae, AD ;

Schmid, S ;

Thompson, JG .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1996, 52 :610-615