In situ surface characterization of preferentially oriented platinum nanoparticles by using electrochemical structure sensitive adsorption reactions

被引：107

作者：

Solla-Gullón, J

Vidal-Iglesias, FJ

Rodríguez, P

Herrero, E

Feliu, JM

Clavilier, J

Aldaz, A

机构：

[1] Univ Alicante, Dept Quim Fis, E-03080 Alicante, Spain

[2] Univ Alicante, Inst Electroquim, E-03080 Alicante, Spain

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2004年 / 108卷 / 36期

关键词：

D O I：

10.1021/jp0471453

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new method for in situ surface characterization of preferentially oriented platinum nanoparticles is presented. The method is based on the use of structure-sensitive surface reactions such as the redox behavior of underpotential and spontaneous deposition of adatoms. Examples of its use for surface characterization of Pt nanoparticles synthesized by different methods are given. The method has been also employed to rationalize the different behavior of these Pt nanoparticles for the ammonia electro-oxidation in a basic medium.

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收藏

页码：13573 / 13575

页数：3

相关论文

共 11 条

[1] Shape-controlled synthesis of colloidal platinum nanoparticles [J].

Ahmadi, TS ;

Wang, ZL ;

Green, TC ;

Henglein, A ;

ElSayed, MA .

SCIENCE, 1996, 272 (5270) :1924-1926

[2] PREPARATION OF MONO-CRYSTALLINE PT MICROELECTRODES AND ELECTROCHEMICAL STUDY OF THE PLANE SURFACES CUT IN THE DIRECTION OF THE (111) AND (110) PLANES [J].

CLAVILIER, J ;

FAURE, R ;

GUINET, G ;

DURAND, R .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1980, 107 (01) :205-209

[3] AN IRREVERSIBLE STRUCTURE SENSITIVE ADSORPTION STEP IN BISMUTH UNDERPOTENTIAL DEPOSITION AT PLATINUM-ELECTRODES [J].

CLAVILIER, J ;

FELIU, JM ;

ALDAZ, A .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 243 (02) :419-433

[4] THE BEHAVIOR OF GERMANIUM ADATOMS IRREVERSIBLY ADSORBED ON PLATINUM SINGLE-CRYSTALS [J].

GOMEZ, R ;

LLORCA, MJ ;

FELIU, JM ;

ALDAZ, A .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 340 (1-2) :349-355

[5] ABSORPTION-SPECTRUM AND SOME CHEMICAL-REACTIONS OF COLLOIDAL PLATINUM IN AQUEOUS-SOLUTION [J].

HENGLEIN, A ;

ERSHOV, BG ;

MALOW, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (38) :14129-14136

[6] Effect of nanocatalysis in colloidal solution on the tetrahedral and cubic nanoparticle SHAPE: Electron-transfer reaction catalyzed by platinum nanoparticles [J].

Narayanan, R ;

El-Sayed, MA .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (18) :5726-5733

[7] Kinetically controlled growth and shape formation mechanism of platinum nanoparticles [J].

Petroski, JM ;

Wang, ZL ;

Green, TC ;

El-Sayed, MA .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (18) :3316-3320

[8] Preparation of palladium and platinum synthetic high polymer catalysts and the relationship between particle size and rate of hydrogenation [J].

Rampino, LD ;

Nord, FF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1941, 63 :2745-2749

[9] Synthesis and electrochemical decontamination of platinum-palladium nanoparticles prepared by water-in-oil microemulsion [J].

Solla-Gullón, J ;

Montiel, V ;

Aldaz, A ;

Clavilier, J .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (02) :E104-E109

[10] Selective electrocatalysis of ammonia oxidation on Pt(100) sites in alkaline medium [J].

Vidal-Iglesias, FJ ;

García-Aráez, N ;

Montiel, V ;

Feliu, JM ;

Aldaz, A .

ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (01) :22-26