Hydrothermal synthesis of iron(III) phosphates in the presence of urea

被引：25

作者：

Trobajo, C ^{[1
]}

Espina, A ^{[1
]}

Jaimez, E ^{[1
]}

Khainakov, SA ^{[1
]}

García, JR ^{[1
]}

机构：

[1] Univ Oviedo, Dept Quim Organ & Inorgan, E-33006 Oviedo, Spain

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 05期

关键词：

D O I：

10.1039/a908854g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Iron(III) phosphates have been synthesized directly under mild hydrothermal conditions. The reaction of FeCl3, H3PO4 and (NH2)(2)CO aqueous solutions at 180 degrees C leads to the formation of four individual compounds: FePO4. 2H(2)O, Fe(NH4)(HPO4)(2), Fe-2(NH4)(OH)(PO4)(2). 2H(2)O and Fe(NH3)(2)PO4. The reaction product depends on the Fe:P:C molar ratio in the reaction mixture. The effect of urea on the reaction route is discussed.

引用

页码：787 / 790

页数：4

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