Gold complexes of trithiocyanuric acid:: A two-dimensional polymer assembled through gold(I)••• gold(I) interactions

被引：56

作者：

Hunks, WJ ^{[1
]}

Jennings, MC ^{[1
]}

Puddephatt, RJ ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 26期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1021/ic991085b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 2,4,6-trithiocyanurate complex [2,4,6-C3N3(SAuL)(3)] is stable when L = triphenylphosphine, but when L = tert-butyl isocyanide, it reacts to give the hexagold(I) complex [{C3N3(AuL)(SAuL)S-2(mu-Au)}(2)]. which contains short intramolecular Au...Au bonds and forms a novel two-dimensional sheet structure through intermolecular Au...Au bonding.

引用

页码：5930 / +

页数：3

共 17 条

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