Direct observation of bonding and charge ordering in (EDO-TTF)2PF6

被引：42

作者：

Aoyagi, S

Kato, K

Ota, A

Yamochi, H

Saito, G

Suematsu, H

Sakata, M

Takata, M ^{[4
]}

机构：

[1] Nagoya Univ, Dept Appl Phys, Nagoya, Aichi 4648603, Japan

[2] Kyoto Univ, Grad Sch Sci, Div Chem, Sakyo Ku, Kyoto 6068502, Japan

[3] Kyoto Univ, Res Ctr Low Temperature & Mat Sci, Sakyo Ku, Kyoto 6068502, Japan

[4] JASRI, SPring8, Sayo, Hyogo 6795198, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 28期

关键词：

charge density; organic conductors; synchrotron; radiation; tetrathiafulvalenes; X-ray diffraction;

D O I：

10.1002/anie.200454075

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dimers of flat (EDO-TTF)+ molecules separated by bent neutral EDO-TTF (ethylenedioxytetrathiafulvalene) molecules are found in the insulator phase of (EDO-TTF)2PF6, but not in that of the metallic phase. The cooperativity of Peierls distortion, charge ordering, and anion ordering in this metal-insulator transition can be regarded as the result of a molecular displacement.

引用

收藏

页码：3670 / 3673

页数：4

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