Matrix effects on the optical response of silver nanoclusters

被引:26
作者
Conus, F. [1 ]
Rodrigues, V. [1 ]
Lecoultre, S. [1 ]
Rydlo, A. [1 ]
Felix, C. [1 ]
机构
[1] Ecole Polytech Fed Lausanne, Inst Phys Nanostruct, CH-1015 Lausanne, Switzerland
关键词
D O I
10.1063/1.2219442
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report absorption spectra for Ag-7, Ag-9, and Ag-11 in an argon matrix grown at a temperature of 28 K and compare them with previous spectra of the same species measured in matrices of argon grown at lower temperatures as well as in neon matrices. We discuss the discrepancies in the light of the matrix crystallinity and show that this leads to an understanding of the influence of the matrix on the optical response of small clusters. (c) 2006 American Institute of Physics.
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页数:4
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