Regioselective opening of epoxides to beta-amido alcohols under solid-liquid PTC conditions

被引：19

作者：

Albanese, D

Landini, D

Penso, M

机构：

[1] Centro CNR, Dipartimento di Chimica Organica, Industriale dell'Università, I-20133 Milano

来源：

TETRAHEDRON | 1997年 / 53卷 / 13期

关键词：

D O I：

10.1016/S0040-4020(97)00162-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A study on the ring opening of a number of epoxides 1 with trifluoroacetamide (2) under solid-liquid phase transfer catalysis (SL-PTC) conditions has been performed. The reaction is completely regioselective affording beta-amido alcohols 3 deriving from the attack of the nucleophile to the less substituted carbon atom of the oxirane ring. (C) 1997 Elsevier Science Ltd.

引用

页码：4787 / 4790

页数：4

共 11 条

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