Novel approach to boron-10 enriched decaborane(14): an important advance in synthetic boron hydride chemistry

被引：9

作者：

Adams, L

Tomlinson, S

Wang, JH

Hosmane, SN

Maguire, JA

Hosmane, NS ^{[1
]}

机构：

[1] No Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA

[2] So Methodist Univ, Dept Chem, Dallas, TX 75275 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 10期

基金：

美国国家科学基金会;

关键词：

boron-10; enriched; pentaborane(9); decaborane(14); Anti-B18H22; synthesis; BNCT; boron hydrides; B-10-NMR;

D O I：

10.1016/S1387-7003(02)00553-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxidative polyhedral cage-fusion reaction of the sodium or lithium salt of the B-10 enriched pentaborate anion, [(B5H8)-B-10](-), with anhydrous FeCl3, NiCl, Br-2, or C5H11Br, followed by room temperature sublimation of the product, produced (B10H14)-B-10 (3) in 52-65% yields. (C) 2002 Elsevier Science B.V. All rights reserved.

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收藏

页码：765 / 767

页数：3

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