Electrocatalytic oxidation of alcohols on glassy carbon electrodes electrochemically modified by conductive polymeric nickel(II) tetrakis(3-methoxy-4-hydroxyphenyl) porphyrin film

被引:82
作者
Ciszewski, A
Milczarek, G
机构
[1] Inst. Chem. and Appl. Electrochem., Poznań Univ. of Technology
来源
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1996年 / 413卷 / 1-2期
关键词
GC modified electrode; electrocatalysis; alcohol oxidation;
D O I
10.1016/0022-0728(96)04616-5
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The electrocatalytic oxidation of methanol and other simple alcohols in alkaline solution at a nickel-based chemically modified glassy carbon electrode was investigated. As a modifier a conductive polymeric nickel(II) tetrakis(3-methoxy-4-hydroxyphenyl)porphyrin film was used. The modified electrode was characterized by cyclic voltammetry, and its analytical utility was checked by using batch injection analysis.
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页码:137 / 142
页数:6
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