Plasmonic photocatalytic system using silver chloride/silver nanostructures under visible light

被引:126
作者
Choi, Moonjung [1 ]
Shin, Kyoung-Hwan [1 ]
Jang, Jyongsik [1 ]
机构
[1] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul 151742, South Korea
关键词
Photocatalyst; Nanostructure; Visible light; Dye decomposition; Silver halide; HIGHLY EFFICIENT; CARBON; NANOMATERIALS; NANOCATALYST; MECHANISM;
D O I
10.1016/j.jcis.2009.09.037
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Plasmonic photocatalytic nanostructured system was investigated on silver chloride/silver nanoparticles under visible light. Silver chloride/silver nanoparticles were readily prepared using dispersing agent and light irradiation. The cl-spacing analysis, high resolution-transmission electron microscopy, X-ray diffraction analysis and diffuse-reflectance spectroscopy demonstrated that silver nanoparticles were introduced on the surface of silver chloride nanoparticles and then silver chloride/silver nanostructured photocatalytic materials were Successfully synthesized. The as-synthesized plasmonic photocatalysts exhibited the enhanced photocatalytic performance over nitrogen-doped titania nanomaterials. The improved catalytic activity was originated from the enhanced adsorption for visible light, electron-hole separation, and the formation of chloride atoms in silver chloride/silver nanostructured materials. (C) 2009 Elsevier Inc. All rights reserved.
引用
收藏
页码:83 / 87
页数:5
相关论文
共 44 条
[1]   Lasting antibacterial activities of Ag-TiO2/Ag/a-TiO2 nanocomposite thin film photocatalysts under solar light irradiation [J].
Akhavan, O. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 336 (01) :117-124
[2]   Effect of PEG on rheology and stability of nanocrystalline titania hydrosols [J].
Alphonse, Pierre ;
Bleta, Rudina ;
Soules, Regis .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 337 (01) :81-87
[3]   A plasmonic photocatalyst consisting of sliver nanoparticles embedded in titanium dioxide [J].
Awazu, Koichi ;
Fujimaki, Makoto ;
Rockstuhl, Carsten ;
Tominaga, Junji ;
Murakami, Hirotaka ;
Ohki, Yoshimichi ;
Yoshida, Naoya ;
Watanabe, Toshiya .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (05) :1676-1680
[4]   The electronic origin of the visible-light absorption properties of C-, N- and S-doped TiO2 nanomaterials [J].
Chen, Xiaobo ;
Burda, Clemens .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (15) :5018-+
[5]   Heavy metal ion adsorption onto polypyrrole-impregnated porous carbon [J].
Choi, Moonjung ;
Jang, Jyongsik .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2008, 325 (01) :287-289
[6]   Photocatalytic degradation of methyl orange using polymer-titania microcomposites [J].
Coutinho, Cecil A. ;
Gupta, Vinay K. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 333 (02) :457-464
[7]  
DEOLIVERIA E, 2009, J COLLOID INTERF SCI, V323, P98
[8]   Interfacial and physico-chemical properties of polymer-supported CdS•ZnS nanocomposites and their role in the visible-light mediated photocatalytic splitting of water [J].
Deshpande, Aparna ;
Shah, Pallavi ;
Gholap, R. S. ;
Gupta, Narendra M. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 333 (01) :263-268
[9]   A highly efficient Ag-ZnO photocatalyst: Synthesis, properties, and mechanism [J].
Georgekutty, Reenamole ;
Seery, Michael K. ;
Pillai, Suresh C. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (35) :13563-13570
[10]  
Glaus S, 2002, CHEM-EUR J, V8, P1785, DOI 10.1002/1521-3765(20020415)8:8<1785::AID-CHEM1785>3.0.CO