One-pot synthesis of functionalized carbacycles by formal [3+3] cyclizations of 1,3-bis(silyl enol ethers) with 1,3-dielectrophiles

被引：134

作者：

Feist, Holger

Langer, Peter

机构：

[1] Univ Rostock, Inst Chem, D-18059 Rostock, Germany

[2] Univ Rostock, Leiniz Inst Katal eV, D-18059 Rostock, Germany

来源：

SYNTHESIS-STUTTGART | 2007年 / 03期

关键词：

arenes; cyclization; one-pot reaction; salicylic acid; silylenol ethers;

D O I：

10.1055/s-2006-958958

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Lewis acid mediated [3+3] cyclizations of 1,3-bis(silyl enol ethers) with 1,3-dielectrophiles, such as 1,1,3,3-tetramethoxypropane, 3-silyloxy-2-en-1-ones and 1,1-diacylcyclopropanes, provide an efficient approach to a variety of functionalized arenes (such as salicylates and phenols) and other six-membered carbacyclic products.

引用

收藏

页码：327 / 347

页数：21

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