Binary diffusion coefficients in supercritical fluids: Recent progress in measurements and correlations for binary diffusion coefficients

被引:47
作者
Funazukuri, Toshitaka
Kong, Chang Yi
Kagei, Seiichiro
机构
[1] Chuo Univ, Dept Appl Chem, Bunkyo Ku, Tokyo 1128551, Japan
[2] Yokohama Natl Univ, Fac Environm & Informat Sci, Hodogaya Ku, Yokohama, Kanagawa 2418501, Japan
关键词
binary diffusion coefficient; chromatographic impulse response; correlation; supercritical; Taylor dispersion;
D O I
10.1016/j.supflu.2006.02.016
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Dr. Aydin Akgerman greatly contributed to studies on diffusion in liquids and supercritical fluids, in particular, measurements by the Taylor dispersion method. Based on his work, this article describes recent progress in measurements for binary diffusion coefficients in supercritical fluids by using the chromatographic impulse response technique as well as the Taylor dispersion method, and in the predictive empirical correlations. The data reported in the literature and the proposed correlations are also briefly reviewed together with the research subjects to be investigated in future. (c) 2006 Published by Elsevier B.V.
引用
收藏
页码:201 / 210
页数:10
相关论文
共 80 条
[1]   Mutual diffusion coefficients of benzene in supercritical carbon dioxide [J].
Ago, K ;
Nishiumi, H .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1999, 32 (05) :563-568
[2]   Limiting diffusion coefficients of heavy molecular weight organic contaminants in supercritical carbon dioxide [J].
Akgerman, A ;
Erkey, C ;
Orejuela, M .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1996, 35 (03) :911-917
[3]  
Alizadeh A., 1980, International Journal of Thermophysics, V1, P243, DOI 10.1007/BF00517126
[4]   ON THE DISPERSION OF A SOLUTE IN A FLUID FLOWING THROUGH A TUBE [J].
ARIS, R .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1956, 235 (1200) :67-77
[5]   BINARY DIFFUSION IN DENSE GASES TO 1360 ATM BY CHROMATOGRAPHIC PEAK-BRAODENING METHOD [J].
BALENOVIC, Z ;
MYERS, MN ;
GIDDINGS, JC .
JOURNAL OF CHEMICAL PHYSICS, 1970, 52 (02) :915-+
[6]   MEASUREMENT AND CORRELATION OF BINARY DIFFUSION-COEFFICIENTS IN NEAR-CRITICAL FLUIDS [J].
CATCHPOLE, OJ ;
KING, MB .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1994, 33 (07) :1828-1837
[7]   TRACER DIFFUSION OF CROWN ETHERS IN NORMAL-DECANE AND NORMAL-TETRADECANE - AN IMPROVED CORRELATION FOR BINARY-SYSTEMS INVOLVING NORMAL ALKANES [J].
CHEN, HC ;
CHEN, SH .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1985, 24 (02) :187-192
[8]  
CUSSLER EL, 1997, DIFFUSION MASS TRANS, P186
[9]   CORRECTED ENSKOG THEORY AND TRANSPORT-COEFFICIENTS OF LIQUIDS [J].
DYMOND, JH .
JOURNAL OF CHEMICAL PHYSICS, 1974, 60 (03) :969-973
[10]   Infinite-dilution diffusion coefficients in supercritical fluids [J].
Eaton, AP ;
Akgerman, A .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1997, 36 (03) :923-931