Stable mononuclear lead(III) compound:: A lead-centered radical

被引：24

作者：

Foerster, Christoph

Klinkhammer, Karl W.

Tumanskii, Boris

Krueger, Hans-Joerg

Kelm, Harald

机构：

[1] Univ Mainz, Inst Anorgan & Analyt Chem, D-55128 Mainz, Germany

[2] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel

[3] Technion Israel Inst Technol, Lise Meitner Minerva Ctr Computat Quantum Chem, IL-32000 Haifa, Israel

[4] Tech Univ Kaiserslautern, Inst Anorgan Chem, D-67663 Kaiserslautern, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 07期

关键词：

EPR spectroscopy; lead; radicals; structure elucidation; X-ray diffraction;

D O I：

10.1002/anie.200603323

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Plumb radical: The kinetically stable plumbyl radical Pb[SiEt(SiMe 3)2]3 (see molecular structure; red Pb, light purple Si, dark purple C) was obtained through oxidation of Pb[SiEt(SiMe 3)2]3- ions. With a half-life of about 8.5 hours at room temperature, it cleanly decomposes to elementary lead and Pb[SiEt(SiMe3)2]4. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1156 / 1159

页数：4

共 21 条

[1]

[Anonymous], 2015, Acta Crystallogr., V71, P3

[2] Synthetic and structural studies ion the cyclic bis(amino)stannylenes Sn[(NR)2C10H6-1,8] and their reactions with SnCl2 or Si[(NCH2But)2C6H4-1,2] (R = SiMe3 or CH2But) [J].