Binary additives synergistically boost the efficiency of all-polymer solar cells up to 3.45%

被引:226
作者
Cheng, Pei [1 ,2 ]
Ye, Long [1 ,3 ,6 ]
Zhao, Xingang [1 ,2 ]
Hou, Jianhui [1 ,3 ]
Li, Yongfang [4 ]
Zhan, Xiaowei [1 ,2 ,5 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
[4] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Jiangsu, Peoples R China
[5] Peking Univ, Coll Engn, Dept Mat Sci & Engn, Beijing 100871, Peoples R China
[6] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
关键词
FIELD-EFFECT TRANSISTORS; SMALL-MOLECULE; PHOTOVOLTAIC DEVICES; SELF-ORGANIZATION; TANDEM POLYMER; PERFORMANCE; MORPHOLOGY; BLENDS; TRANSPORT; VOLTAGE;
D O I
10.1039/c3ee43041c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Binary additives synergistically boost the power conversion efficiency of all-polymer solar cells up to 3.45%. The nonvolatile additive PDI-2DTT suppresses aggregation of the acceptor PPDIDTT and enhances donor/acceptor mixing, while the additive DIO facilitates aggregation and crystallization of the donor PBDTTT-C-T as well as improves phase separation. Combination of DIO and PDI-2DTT leads to suitable phase separation and improved and balanced charge transport, which is beneficial to efficiency enhancement.
引用
收藏
页码:1351 / 1356
页数:6
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