Synthesis and characterization of different nanostructured copper(II) metal-organic frameworks by a ligand functionalization and modulation method

被引：13

作者：

Alavi, Mohammad Amin ^{[1
]}

Morsali, Ali ^{[1
]}

机构：

[1] Tarbiat Modares Univ, Dept Chem, Tehran, Iran

来源：

CRYSTENGCOMM | 2014年 / 16卷 / 11期

关键词：

ATOMIC-FORCE MICROSCOPY; COORDINATION POLYMERS; ORIENTED ATTACHMENT; HYDROGEN STORAGE; CRYSTAL-GROWTH; NANOCRYSTALS; ADSORPTION; SEPARATION; SITES;

D O I：

10.1039/c3ce42390e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanorods of {[Cu-2(BDC)(2)(dabco)]center dot 2DMF center dot 2H(2)O} (1) and nanotubes of {[Cu-2(BDC-NH2)center dot(2)(d-bco)]center dot 2DMF center dot 2H(2)O} (2) h-ve been synthesized vi- re-ction of copper(II) -cet-te with terephth-lic -cid -nd -minoterephth-lic -cid in the presence of triethylenedi-mine -s the pill-r lig-nd -nd -cetic -cid -s the modul-tor. Form-tion of the unexpected n-notube morphology inste-d of n-norods w-s evidenced when -minobenzene- 1,4- dic-rboxyl-te [BDC- NH2] w-s used inste-d of the benzene- 1,4- dic-rboxyl-te (BDC) lig-nd. N-norods -nd n-notubes of compounds 1 -nd 2, respectively, were ch-r-cterized by sc-nning electron microscopy (SEM), tr-nsmission electron microscopy (TEM), X- r-y powder diffr-ction (XRD) -nd BET -n-lyses.

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页码：2246 / 2250

页数：5

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共 24 条

[1] Zinc(II) nitrite coordination polymers based on rigid and flexible organic nitrogen donor ligands [J].

Amiri, Maryam Ghoreishi ;

Mahmoudi, Ghodrat ;

Morsali, Ali ;

Hunter, Allen D. ;

Zeller, Matthias .

CRYSTENGCOMM, 2007, 9 (08) :686-697

[2] Mechanical gas capture and release in a network solid via multiple single-crystalline transformations [J].

Chandler, Brett D. ;

Enright, Gary D. ;

Udachin, Konstantin A. ;

Pawsey, Shane ;

Ripmeester, John A. ;

Cramb, David T. ;

Shimizu, George K. H. .

NATURE MATERIALS, 2008, 7 (03) :229-235

[3] Hydrogen storage in microporous metal-organic frameworks with exposed metal sites [J].

Dinca, Mircea ;

Long, Jeffrey R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (36) :6766-6779

[4] Hydrogen storage in a microporous metal-organic framework with exposed Mn2+ coordination sites [J].

Dinca, Mircea ;

Dailly, Anne ;

Liu, Yun ;

Brown, Craig M. ;

Neumann, Dan. A. ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) :16876-16883

[5] Crystallized frameworks with giant pores:: Are there limits to the possible? [J].

Férey, G ;

Mellot-Draznieks, C ;

Serre, C ;

Millange, F .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :217-225

[6] Coordination Modulation Induced Synthesis of Nanoscale Eu1-xTbx-Metal-Organic Frameworks for Luminescent Thin Films [J].

Guo, Hailing ;

Zhu, Yongzhong ;

Qiu, Shilun ;

Lercher, Johannes A. ;

Zhang, Hongjie .

ADVANCED MATERIALS, 2010, 22 (37) :4190-+

[7] Trapping metal-organic framework nanocrystals:: An in-situ time-resolved light scattering study on the crystal growth of MOF-5 in solution [J].

Hermes, Stephan ;

Witte, Thomas ;

Hikov, Todor ;

Zacher, Denise ;

Bahnmueller, Stefan ;

Langstein, Gerhard ;

Huber, Klaus ;

Fischer, Roland A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (17) :5324-+

[8] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

[9] Modular Synthesis of Functional Nanoscale Coordination Polymers [J].

Lin, Wenbin ;

Rieter, William J. ;

Taylor, Kathryn M. L. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (04) :650-658

[10] Morphological study and potential applications of nano metal-organic coordination polymers [J].

Masoomi, Mohammad Yaser ;

Morsali, Ali .

RSC ADVANCES, 2013, 3 (42) :19191-19218