Synthesis of 2-arylpropionic acids by electrocarboxylation of benzylchlorides catalysed by PdCl2(PPh3)2

被引：39

作者：

Damodar, J ^{[1
]}

Mohan, SRK ^{[1
]}

Reddy, SRJ ^{[1
]}

机构：

[1] Sri Venkateswara Univ, Dept Chem, Electrochem Res Labs, Tirupati 517502, Andhra Pradesh, India

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2001年 / 3卷 / 12期

关键词：

methylarylhalide; carbon dioxide; carboxylic acid; palladium complex; catalysis; cyclic voltammetry;

D O I：

10.1016/S1388-2481(01)00263-6

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Electrochemical carboxylation of benzylchlorides catalysed by Pd(II) complex afforded 2-arylpropionic acids in good yields under atmospheric pressure of carbon dioxide at constant current of 10 mA cm(-2). Mechanistic and electrochemical studies revealed the cooperative role of reduced palladium species in the activation of carbon dioxide. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：762 / 766

页数：5

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