Large-scale synthesis of single-wall carbon nanotubes by catalytic chemical vapor deposition (CCVD) method

被引：435

作者：

Colomer, JF

Stephan, C

Lefrant, S

Van Tendeloo, G

Willems, I

Kónya, Z

Fonseca, A

Laurent, C

Nagy, JB

机构：

[1] Fac Univ Notre Dame Paix, Lab Resonance Magnet Nucl, B-5000 Namur, Belgium

[2] Univ Nantes, IMN, F-44322 Nantes 3, France

[3] Univ Antwerp, EMAT, RUCA, B-2020 Antwerp, Belgium

[4] Univ Toulouse 3, Lab Chim Mat Inorgan, ESA CNRS 5070, F-31062 Toulouse 4, France

来源：

CHEMICAL PHYSICS LETTERS | 2000年 / 317卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(99)01338-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The large-scale production of single-wall carbon nanotubes (SWNTs) is reported. Large quantities of SWNTs can be synthesised by catalytic decomposition of methane over well-dispersed metal particles supported on MgO at 1000 degrees C. The thus produced SWNTs can be separated easily from the support by a simple acidic treatment to obtain a product with high yields (70-80%) of SWNTs. Because the typical synthesis time is 10 min, 1 g of SWNTs can be synthesised per day by this method. The SWNTs are characterized by high-resolution transmission electron microscopy and by Raman spectroscopy, showing the quality and the quantity of products. (C) 2000 Elsevier Science B.V. All rights reserved.

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页码：83 / 89

页数：7

相关论文

共 16 条

[1] Effect of the growth temperature on the diameter distribution and chirality of single-wall carbon nanotubes [J].

Bandow, S ;

Asaka, S ;

Saito, Y ;

Rao, AM ;

Grigorian, L ;

Richter, E ;

Eklund, PC .

PHYSICAL REVIEW LETTERS, 1998, 80 (17) :3779-3782

[2] Scanning tunneling microscope investigation of carbon nanotubes produced by catalytic decomposition of acetylene [J].

Biro, LP ;

Lazarescu, S ;

Lambin, P ;

Thiry, PA ;

Fonseca, A ;

Nagy, JB ;

Lucas, AA .

PHYSICAL REVIEW B, 1997, 56 (19) :12490-12498

[3] Large-scale and low-cost synthesis of single-walled carbon nanotubes by the catalytic pyrolysis of hydrocarbons [J].

Cheng, HM ;

Li, F ;

Su, G ;

Pan, HY ;

He, LL ;

Sun, X ;

Dresselhaus, MS .

APPLIED PHYSICS LETTERS, 1998, 72 (25) :3282-3284

[4] Synthesis of single-wall carbon nanotubes by catalytic decomposition of hydrocarbons [J].

Colomer, JF ;

Bister, G ;

Willems, I ;

Kónya, Z ;

Fonseca, A ;

Van Tendeloo, G ;

Nagy, JB .

CHEMICAL COMMUNICATIONS, 1999, (14) :1343-1344

[5] Single-wall nanotubes produced by metal-catalyzed disproportionation of carbon monoxide [J].

Dal, HJ ;

Rinzler, AG ;

Nikolaev, P ;

Thess, A ;

Colbert, DT ;

Smalley, RE .

CHEMICAL PHYSICS LETTERS, 1996, 260 (3-4) :471-475

[6] Synthesis of single-walled carbon nanotubes using binary (Fe, Co, Ni) alloy nanoparticles prepared in situ by the reduction of oxide solid solutions [J].

Flahaut, E ;

Govindaraj, A ;

Peigney, A ;

Laurent, C ;

Rousset, A ;

Rao, CNR .

CHEMICAL PHYSICS LETTERS, 1999, 300 (1-2) :236-242

[7]

FLAHAUT E, 2000, IN PRESS J MAT CHEM, V10

[8] Catalytic growth of single-wall carbon nanotubes from metal particles [J].

Hafner, JH ;

Bronikowski, MJ ;

Azamian, BR ;

Nikolaev, P ;

Rinzler, AG ;

Colbert, DT ;

Smith, KA ;

Smalley, RE .

CHEMICAL PHYSICS LETTERS, 1998, 296 (1-2) :195-202

[9] Catalytic production and purification of nanotubules having fullerene-scale diameters [J].

Ivanov, V ;

Fonseca, A ;

Nagy, JB ;

Lucas, A ;

Lambin, P ;

Bernaerts, D ;

Zhang, XB .

CARBON, 1995, 33 (12) :1727-1738

[10] Large-scale production of single-walled carbon nanotubes by the electric-arc technique [J].

Journet, C ;

Maser, WK ;

Bernier, P ;

Loiseau, A ;

delaChapelle, ML ;

Lefrant, S ;

Deniard, P ;

Lee, R ;

Fischer, JE .

NATURE, 1997, 388 (6644) :756-758