C-glycosidic flavonoids from Cassia occidentalis

被引:39
作者
Hatano, T [1 ]
Mizuta, S [1 ]
Ito, H [1 ]
Yoshida, T [1 ]
机构
[1] Okayama Univ, Fac Pharmaceut Sci, Okayama 7008530, Japan
关键词
Cassia occidentalis; Leguminosae; cassiaoccidentalin A; cassiaoccidentalin B; cassiaoccidentalin C; flavonoid; conformation;
D O I
10.1016/S0031-9422(99)00437-9
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Three new C-glycosidic flavonoids, cassiaoccidentalins A, B and C, were isolated from aerial parts of Cassia occidentalis and their structures with a 3-keto sugar were established on the basis of spectroscopic and chemical evidence. They showed signals of two conformers in their H-1- and C-13-NMR spectra due to hindered rotation around their C-glycosidic linkages, and the conformations in solution were analyzed by NMR spectroscopic analyses. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1379 / 1383
页数:5
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