The first indium-organic two-dimensional layer network with rhombus grids

被引：30

作者：

Lin, ZZ ^{[1
]}

Luo, JH ^{[1
]}

Hong, MC ^{[1
]}

Wang, RH ^{[1
]}

Han, L ^{[1
]}

Cao, R ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2004年 / 177卷 / 07期

基金：

中国国家自然科学基金; 中国科学院基金;

关键词：

hydrothermal synthesis; crystal structure; indium (III); 1,3,5-benzenctricarboxylate; 4,4'-bipyridine;

D O I：

10.1016/j.jssc.2004.04.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The indium(Ill)-organic compound [In(HBtc)(2)(4,4'-bpy)](4,4'-Hbpy)(H2O)(0.5) (Btc = 1,3,5-benzenetricarboxylate, 4,4'-bpy = 4,4'-bipyridine) has been synthesized under hydrothermal condition and characterized by IR, fluorescent spectroscopy, TGA and single-crystal X-ray diffraction analyses. The compound crystallizes in monoclinic, space group P2(1)/c, a = 17.0884(2) Angstrom, b = 12.28390(10) Angstrom, c = 17.9456(4) Angstrom, beta = 104.1920(10)degrees, V = 3652.03(10) Angstrom(3), Z = 4, R-1 = 0.0572 and wR(2) = 0.1116 [I>2sigma(I)]. All the indium, atoms in the compound are hepta-coordinated and link 1,3,5-benzenetricarboxylate forming a 2-D layer structure with rhombus grids. (C) 2004 Elsevier Inc. All rights reserved.

引用

页码：2494 / 2498

页数：5

共 23 条

[1] Novel lanthanide(III) coordination polymers with 1,4-bis(phenyl-sulfinyl)butane forming unique lamellar square array: Syntheses, crystal structures, and properties [J].