Absorption of mercury in gold films and its further desorption: Quantitative morphological study of the surface patterns

被引:21
作者
Fialkowski, M
Grzeszczak, P
Nowakowski, R
Holyst, R
机构
[1] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
[2] Cardinal Stefan Wyszynski Univ, Coll Sci, Dept Math & Nat Sci, PL-01815 Warsaw, Poland
关键词
D O I
10.1021/jp0365413
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A thin film of Au exposed to mercury vapor disrupts forming separated domains of AuHg amalgam. After evaporation of Hg at high temperature An islands are formed and the domain pattern changes. A detailed quantitative morphological analysis and comparison of two types of surface patterns before and after the evaporation of Hg is performed. We have found that during the evaporation of Hg at high temperature the islands decrease their sizes and their shapes become more circular. The domain pattern formed by the amalgam domains is found to be characterized by one length scale. After the removal of mercury the characteristic length scale vanishes and the structure function takes the shape typical for the random droplet morphologies.
引用
收藏
页码:5026 / 5030
页数:5
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