Chiral inclusion crystals constructed with achiral host and achiral guest molecules

被引：4

作者：

Toda, F ^{[1
]}

机构：

[1] Okayama Univ Sci, Fac Sci, Dept Chem, Okayama 7000005, Japan

来源：

ENANTIOMER | 2002年 / 7卷 / 2-3期

关键词：

chiral inclusion crystals; generation of chirality in crystal; optical resolution; CD spectra in Nujol mulls; chiral helix; chiral twisting in crystal;

D O I：

10.1080/10242430212198

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Achiral molecules of tetrakis(p-bromophenyl)ethylene and 2,3,6,7,10,11-hexahydroxy triphenylene were found to arrange in a chiral form in their inclusion crystal with an achiral guest molecule. The chiral arrangement of these achiral molecules was studied by X-ray analysis and CD spectral measurement in the solid state.

引用

页码：59 / 65

页数：7

共 9 条

[1]

Farina A, 1999, ANGEW CHEM INT EDIT, V38, P2433, DOI 10.1002/(SICI)1521-3773(19990816)38:16<2433::AID-ANIE2433>3.3.CO

[2]

2-4

[3] ABSOLUTE ASYMMETRIC-SYNTHESIS BY IRRADIATION OF CHIRAL CRYSTALS [J].

KAUPP, G ;

HAAK, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (05) :694-695

[4] Absolute asymmetric synthesis from achiral molecules in the chiral crystalline environment [J].

Sakamoto, M .

CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (05) :684-689

[5] Solvent-free organic synthesis [J].

Tanaka, K ;

Toda, F .

CHEMICAL REVIEWS, 2000, 100 (03) :1025-1074

[6] Chiral inclusion crystallization of tetra(p-bromophenyl)ethylene by exposure to the vapor of achiral guest molecules:: a novel racemic-to-chiral transformation through gas-solid reaction [J].

Tanaka, K ;

Fujimoto, D ;

Oeser, T ;

Irngartinger, H ;

Toda, F .

CHEMICAL COMMUNICATIONS, 2000, (05) :413-414

[7] Chiral inclusion crystallization of achiral tetrakis(p-halophenyl)-ethylenes with achiral guest compounds [J].

Tanaka, K ;

Fujimoto, D ;

Altreuther, A ;

Oeser, T ;

Irngartinger, H ;

Toda, F .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2000, (10) :2115-2120

[8]

Toda F, 2000, J PHYS ORG CHEM, V13, P39, DOI 10.1002/(SICI)1099-1395(200001)13:1<39::AID-POC203>3.0.CO

[9]

2-8

← 1 →