A versatile, transition-metal mediated route to blue-light-emitting polymers with chemically tunable luminescent properties

被引:117
作者
Mao, SSH [1 ]
Tilley, TD [1 ]
机构
[1] UNIV CALIF BERKELEY, DEPT CHEM, BERKELEY, CA 94720 USA
关键词
D O I
10.1021/ma9701402
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The zirconocene coupling of conjugated dines is a versatile route to a new family of polymers with primarily cross-conjugated structures. This partially cross-conjugated and irregular structure result in the relatively wide band gaps of the polymers which appear to be responsible for the observed emission of blue light.
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页码:5566 / 5569
页数:4
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