NOx reduction over CeO2-ZrO2 supported iridium catalyst in the presence of propanol

被引:19
作者
Baudin, F
Da Costa, P
Thomas, C
Calvo, S
Lendresse, Y
Schneider, S
Delacroix, F
Plassat, G
Djéga-Mariadassou, G
机构
[1] Univ Paris 06, CNRS, Lab React Surface, UMR 7609, F-75252 Paris 05, France
[2] Renault SA, Technoctr Renault, F-78280 Guyancourt, France
[3] PSA Peugeot Citroen, F-92250 La Garenne Colombes, France
[4] ADEME, F-49004 Angers, France
[5] ADEME, F-06500 Valbonne, France
关键词
Ir/Ce0.6Zr0.4O2; catalyst; lean deNO(x); 1-propanol; TPSR; isothermal reaction; FTIR;
D O I
10.1023/B:TOCA.0000029735.00981.75
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The 1-propanol assisted-reduction of NOx was investigated over Ir/Ce0.6Zr0.4O2. The catalytic performances of such a catalyst, the associated FTIR characterizations, and transient experiments suggest the formation of adsorbed R-NOx species as intermediates of the deNO(x) process; they provide the partially oxidized species required by the deNO(x) model.
引用
收藏
页码:97 / 101
页数:5
相关论文
共 19 条
[1]   Selective catalytic reduction of nitric oxide by hydrocarbons [J].
Amiridis, MD ;
Zhang, TJ ;
Farrauto, RJ .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1996, 10 (1-3) :203-227
[2]  
BERGER M, 2000, THESIS U P M CURIE P
[3]   A review of the selective reduction of NOx, with hydrocarbons under lean-burn conditions with non-zeolitic oxide and platinum group metal catalysts [J].
Burch, R ;
Breen, JP ;
Meunier, FC .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 39 (04) :283-303
[4]   A general model for both three-way and deNOx catalysis:: dissociative or associative nitric oxide adsorption, and its assisted decomposition in the presence of a reductant Part I.: Nitric oxide decomposition assisted by CO over reduced or oxidized rhodium species supported on ceria [J].
Djéga-Mariadassou, G ;
Fajardie, F ;
Tempère, JF ;
Manoli, JM ;
Touret, O ;
Blanchard, G .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 161 (1-2) :179-189
[5]   The current state of research on automotive lean NOx catalysis [J].
Fritz, A ;
Pitchon, V .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1997, 13 (01) :1-25
[6]   Mechanistic studies of NOx reduction reactions under oxidative atmosphere on alumina supported 1wt%Pt and 1wt%Pt-0.5wt%Zn catalysts (Part I) [J].
Garin, F ;
Girard, P ;
Ringler, S ;
Maire, G ;
Davias, N .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1999, 20 (03) :205-218
[7]  
Gorce O., 2001, 2001013508 SAE 2001013508 SAE
[8]  
Held W., 1990, SAE T, P209
[9]  
Iwamoto M., 1990, SHOKUBAI, V32, P430
[10]  
JOUBERT E, 2000, 5 INT C CAT AUT POLL, V2, P149