Supramolecular electrode materials derived from pyrrole-substituted ruthenium(II) bipyridyl calix[4]arenes

被引：13

作者：

Bettega, HCY

Hissler, M

Moutet, JC

Ziessel, R

机构：

[1] UNIV GRENOBLE 1,LAB ELECTROCHIM ORGAN,F-38041 GRENOBLE 9,FRANCE

[2] UNIV GRENOBLE 1,UMR CNRS 5630,F-38041 GRENOBLE 9,FRANCE

[3] ECOLE CHIM POLYMERES MAT STRASBOURG,LAB CHIM ELECT & PHOTON MOL,UMR CNRS 46,F-67008 STRASBOURG,FRANCE

来源：

CHEMISTRY OF MATERIALS | 1997年 / 9卷 / 01期

关键词：

D O I：

10.1021/cm9603112

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first example of electropolymerization of calixarenes functionalized with pendant polypyridyl ruthenium(II) complexes to produce poly(calixarene-[Ru(bpy)(3)](2+)) modified electrodes is described; the coating of electrodes was achieved by oxidative homo- and copolymerization, with N-methylpyrrole, of the monomer complexes, and by an original process making use of the electropolymerization of a film formed upon adsorption and accumulation on the electrode surface of the reduced complexes.

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页码：3 / &

页数：4

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