Preparation of isolable ion-radical salt derived from TTF-based spin-polarized donor

被引：39

作者：

Nakazaki, J

Ishikawa, Y

Izuoka, A

Sugawara, T

Kawada, Y

机构：

[1] Univ Tokyo, Grad Sch Arts & Sci, Dept Basic Sci, Meguro Ku, Tokyo 1538902, Japan

[2] Ibaraki Univ, Fac Sci, Dept Chem, Bunkyo Ku, Mito, Ibaraki 3108512, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2000年 / 319卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(00)00143-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Galvanostatic electrocrystallization of a TTF-based donor-radical (ETBN) has afforded an ion-radical salt. The radical site of ETBN is intact in the prepared salt and showed paramagnetic behavior. The salt is a semiconductor with conductivity of 10(-2) S/cm at room temperature. Conductivity and magnetic properties are explained as a new type of an ion-radical salt derived from a pi-conjugated donor-radical. (C) 2000 Elsevier Science B.V. All rights reserved.

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页码：385 / 390

页数：6

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