Highly stereoselective oxidative esterification of aldehydes with β-dicarbonyl compounds

被引：86

作者：

Yoo, Woo-Jin ^{[1
]}

Li, Chao-Jun ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 16期

关键词：

D O I：

10.1021/jo0606103

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper-catalyzed oxidative esterification of aldehydes with beta-dicarbonyl compounds was developed using tert-butyl hydroperoxide as an oxidant. In general, the enol esters were synthesized in good yields ( up to 87%) and high stereoselectivity under the optimized reaction conditions.

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页码：6266 / 6268

页数：3

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