Formation of a Thermally Stable, Porous Coordination Network via a Crystalline-to-Amorphous-to-Crystalline Phase Transition

被引：74

作者：

Ohara, Kazuaki ^{[1
]}

Marti-Rujas, Javier ^{[1
]}

Haneda, Tsuyoshi ^{[1
]}

Kawano, Masaki ^{[1
]}

Hashizume, Daisuke ^{[2
]}

Izumi, Fujio ^{[3
]}

Fujita, Makoto ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[2] RIKEN, Adv Technol Support Div, Wako, Saitama 3510198, Japan

[3] Natl Inst Mat Sci, Quantum Beam Ctr, Tsukuba, Ibaraki 3050044, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 11期

基金：

日本学术振兴会;

关键词：

METAL-ORGANIC FRAMEWORK; X-RAY-DIFFRACTION; GUEST REMOVAL; POLYMERS; STABILITY; EXCHANGE; SOLIDS; DESIGN;

D O I：

10.1021/ja9005145

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A porous coordination network was cleanly obtained after a crystalline-to-amorphous-to-crystalline phase transition, and the crystal structure was unambiguously solved by ab initio powder X-ray diffraction. After the solid-state phase transition, the porous structure was remarkably stable up to 673 K and capable of reabsorbing various guest molecules, such as aromatic solvents and I-2.

引用

页码：3860 / +

页数：4

共 35 条

[1]

[Anonymous], 2002, IUCR MONOGRAPHS CRYS

[2]

[Anonymous], ANGEW CHEM

[3]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[4]

2-Z

[5]

Biradha K, 2002, ANGEW CHEM INT EDIT, V41, P3392, DOI 10.1002/1521-3773(20020916)41:18<3392::AID-ANIE3392>3.0.CO

[6]

2-V

[7]

Biradha K, 2002, ANGEW CHEM INT EDIT, V41, P3395, DOI 10.1002/1521-3773(20020916)41:18<3395::AID-ANIE3395>3.0.CO

[8]

2-D

[9]

Biradha K, 2000, ANGEW CHEM INT EDIT, V39, P3843, DOI 10.1002/1521-3773(20001103)39:21<3843::AID-ANIE3843>3.0.CO

[10]

2-#

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