Mechanically induced expeditious and selective preparation of disubstituted pyridine/pyrimidine ferrocenyl complexes

被引：58

作者：

Braga, D

D'Addario, D

Polito, M

Grepioni, F

机构：

[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

[2] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 11期

关键词：

D O I：

10.1021/om049958j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Disubstituted pyridine / pyrimidine ferrocenyl complexes have been obtained by mechanically induced Sukuzi coupling reactions in the solid state. It is shown that the solventless process is much faster, and more selective, than the same reaction carried out in solution. The synthesis and structure of the complex [Fe(eta(5)-C5H4-4-C5H4N)(eta(5)-C5H4-3-C4H3N2)] are reported as a test case.

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页码：2810 / 2812

页数：3

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