Synthesis, characterization and spectroscopic properties of [Cu-I(alkylisocyanide)(4)]BF4 complexes. X-ray crystal structures of [Cu(MIBI)(4)]BF4 and [Cu(CPI)(4)]BF4

被引：12

作者：

Deicas, B

Gambino, D

Kremer, C

Kremer, E

Mombru, A

Suescun, L

Mariezcurrena, R

Gonzalez, O

Rey, A

Mallo, L

Leon, A

机构：

[1] FAC QUIM MONTEVIDEO,CATEDRA QUIM INORGAN,MONTEVIDEO,URUGUAY

[2] FAC QUIM MONTEVIDEO,CATEDRA FIS,LAB CRISTALOG,MONTEVIDEO,URUGUAY

[3] FAC CIENCIAS,CTR INVEST NUCL,DEPT RADIOFARM,MONTEVIDEO,URUGUAY

来源：

POLYHEDRON | 1997年 / 16卷 / 14期

关键词：

copper(I) complexes; copper(I) alkylisocyanide complexes; structure of [Cu(MIBI)(4)]BF4; structure of [Cu(CPI)(4)]BF4;

D O I：

10.1016/S0277-5387(96)00566-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Alkylisocyanide complexes of copper(I) with formula [Cu(CNR)(4)]BF4 [where R = 2-methoxyisobutyl and 2-(carbomethoxy)-2-methylethyl] were synthesized by direct reaction of cuprous chloride with ligand. The stability of solid complexes and their aqueous solutions were tested by HPLC. Comparative studies were carried out on electronic, IR and H-1 NMR spectroscopy. Crystal structures of [Cu(MIBI)(4)]BF4 and [Cu(CPI)(4)]BF4 were determined from X-ray data and show a tetrahedral arrangement of ligands around the central copper atom in both compounds. (C) 1997 Elsevier Science Ltd.

引用

页码：2397 / 2403

页数：7

共 20 条

[1] A phase rule study of the cupro-, argento-, auro- and thallo-cyanides of potassium [J].