Intrazeolite photo-oxygenation of (R)-(-)-α-phellandrene

被引：8

作者：

Stratakis, M ^{[1
]}

Sofikiti, N ^{[1
]}

机构：

[1] Univ Crete, Dept Chem, Iraklion 71409, Greece

来源：

JOURNAL OF CHEMICAL RESEARCH | 2002年 / 08期

关键词：

intrazeolite photo-oxygenation; (R)-(-)-alpha-phellandrene;

D O I：

10.3184/030823402103172356

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thionin-sensitised intrazeolite photo-oxygenation of (R)-(-)-alpha-phellandrene affords (1S,5R)-5-(1-methylethyl)-2-methylidene-3-cyclohexen-1-yl hydroperoxide as the major ene product. This can be easily reduced with triphenylphosphine to the natural product trans-yabunikkeol.

引用

收藏

页码：374 / 375

页数：2

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