Template synthesis of nanoparticle arrays of gold and platinum in mesoporous silica films

被引:135
作者
Fukuoka, A [1 ]
Araki, H
Sakamoto, Y
Sugimoto, N
Tsukada, H
Kumai, Y
Akimoto, Y
Ichikawa, M
机构
[1] Hokkaido Univ, Grad Sch Sci, Catalysis Res Ctr, Sapporo, Hokkaido 0600811, Japan
[2] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600811, Japan
[3] Toyota Cent Res & Dev Labs Inc, Aichi, Japan
关键词
D O I
10.1021/nl0256107
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mesoporous silica films work as templates to form uniform nanoparticles of Au and Pt. The composite materials form an array of metal nanoparticles (diameter ca. 2.5 nm) in the one-dimensional mesopores (pore diameter 2.7 nm), showing an ordered structure in the TEM observation. The nanoparticles are isolated from the silica film by dissolving with a diluted HF solution, and in the presence of 1-dodecanethiol unsupported Au nanoparticles form a superlattice structure.
引用
收藏
页码:793 / 795
页数:3
相关论文
共 28 条
[1]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[2]   3D quantum dot lattice inside mesoporous silica films [J].
Besson, S ;
Gacoin, T ;
Ricolleau, C ;
Jacquiod, C ;
Boilot, JP .
NANO LETTERS, 2002, 2 (04) :409-414
[3]   Novel templating synthesis of necklace-shaped mono- and bimetallic nanowires in hybrid organic-inorganic mesoporous material [J].
Fukuoka, A ;
Sakamoto, Y ;
Guan, S ;
Inagaki, S ;
Sugimoto, N ;
Fukushima, Y ;
Hirahara, K ;
Iijima, S ;
Ichikawa, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (14) :3373-3374
[4]  
FUKUOKA A, 2001, MICROPOROUS MESOSPOR, V48, P597
[5]   An in situ study of mesostructured CTAB-silica film formation during dip coating using time-resolved SAXS and interferometry measurements [J].
Grosso, D ;
Babonneau, F ;
Albouy, PA ;
Amenitsch, H ;
Balkenende, AR ;
Brunet-Bruneau, A ;
Rivory, J .
CHEMISTRY OF MATERIALS, 2002, 14 (02) :931-939
[6]   Preparation of noble metal nanowires using hexagonal mesoporous silica SBA-15 [J].
Han, YJ ;
Kim, JM ;
Stucky, GD .
CHEMISTRY OF MATERIALS, 2000, 12 (08) :2068-2069
[7]   Chemistry and physics in one dimension: Synthesis and properties of nanowires and nanotubes [J].
Hu, JT ;
Odom, TW ;
Lieber, CM .
ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (05) :435-445
[8]   Ag nanowire formation within mesoporous silica [J].
Huang, MH ;
Choudrey, A ;
Yang, PD .
CHEMICAL COMMUNICATIONS, 2000, (12) :1063-1064
[9]   SYNTHESIS OF HIGHLY ORDERED MESOPOROUS MATERIALS FROM A LAYERED POLYSILICATE [J].
INAGAKI, S ;
FUKUSHIMA, Y ;
KURODA, K .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (08) :680-682
[10]   Novel mesoporous materials with a uniform distribution of organic groups and inorganic oxide in their frameworks [J].
Inagaki, S ;
Guan, S ;
Fukushima, Y ;
Ohsuna, T ;
Terasaki, O .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) :9611-9614