A facile surfactant-free method to the synthesis of tip-ended VO2 nanorods in high yield

被引：23

作者：

Li, Beibei

Ni, Xiaomin

Zhou, Fu

Cheng, Jing

Zheng, Huagui

Ji, Mingrong ^{[1
]}

机构：

[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China

[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

来源：

SOLID STATE SCIENCES | 2006年 / 8卷 / 10期

关键词：

oxides; crystal growth; X-ray diffraction; electrochemical properties;

D O I：

10.1016/j.solidstatesciences.2006.05.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A facile surfactant-free route was reported for the synthesis of novel tip-ended B phase VO2 nanorods in high yield. These nanorods, with the growth orientation along the [001] direction, had average diameters of about 100 nm and 3-5 mu m in length. A new cracking-crystallization mechanism was proposed for the formation of the nanorods based on time-dependent transmission electron microscopy (TEM) studies of the product evolution. Electrochemical test results showed thus-prepared nanorods Of VO2 (B) delivered the specific discharge capacity as high as 320 mAh(.)g(-1). (c) 2006 Elsevier Masson SAS. All rights reserved.

引用

收藏

页码：1168 / 1172

页数：5

相关论文

共 14 条

[1] Electrochromic devices on polyester foil [J].

Azens, A ;

Gustavsson, G ;

Karmhag, R ;

Granqvist, CG .

SOLID STATE IONICS, 2003, 165 (1-4) :1-5

[2] Synthesis and characterization of novel vanadium dioxide nanorods [J].

Chen, W ;

Peng, JF ;

Mai, LQ ;

Yu, H ;

Qi, YY .

SOLID STATE COMMUNICATIONS, 2004, 132 (08) :513-516

[3]

Christian P. A., 1980, US Patent, Patent No. 4228226

[4] A new metastable phase of needle-like nanocrystalline VO2 • H2O and phase transformation [J].

Gui, Z ;

Fan, R ;

Chen, XH ;

Wu, YC .

JOURNAL OF SOLID STATE CHEMISTRY, 2001, 157 (02) :250-254

[5] Electronic properties of the VO2(011) surface:: density functional cluster calculations [J].

Haras, A ;

Witko, M ;

Salahub, DR ;

Hermann, K ;

Tokarz, R .

SURFACE SCIENCE, 2001, 491 (1-2) :77-87

[6] Synthesis and electrochemical evaluation of high capacity nanostructured VO2 cathodes [J].

Kannan, AM ;

Manthiram, A .

SOLID STATE IONICS, 2003, 159 (3-4) :265-271

[7] Stable Pd/V2O5 optical H2 sensor [J].

Liu, P ;

Lee, SH ;

Cheong, HM ;

Tracy, CE ;

Pitts, JR ;

Smith, RD .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (03) :H76-H80

[8] Alumina-supported vanadium nanoparticles:: Structural characterization and CO adsorption properties [J].

Magg, N ;

Giorgi, JB ;

Frank, MM ;

Immaraporn, B ;

Schroeder, T ;

Bäumer, M ;

Freund, HJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (11) :3616-3626

[9] Sonochemical synthesis of trigonal selenium nanowires [J].

Mayers, BT ;

Liu, K ;

Sunderland, D ;

Xia, YN .

CHEMISTRY OF MATERIALS, 2003, 15 (20) :3852-3858

[10] Synthesis and electrochemical properties of vanadium oxide aerogels prepared by a freeze-drying process [J].

Sudant, G ;

Baudrin, E ;

Dunn, B ;

Tarascon, JM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (05) :A666-A671