Living polymerization of propene with a chelating (diamide)dimethyltitanium complex using silica-supported methylaluminoxane

被引：23

作者：

Hagimoto, H ^{[1
]}

Shiono, T ^{[1
]}

Ikeda, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

MACROMOLECULES | 2002年 / 35卷 / 15期

关键词：

D O I：

10.1021/ma025535m

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A living polymerization system, in which neither chain transfer reaction nor deactivation occurs, affords polymers with predictable molecular weights and marrow molecular weight distribution. Hence, the living polymerization has attracted much attention for synthesizing terminally functionalized polymers and block copolymers. This paper focuses on the heterogenization of this system to achieve a well-defined supported catalyst for living polymerization of propene.

引用

页码：5744 / 5745

页数：2

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