Base-promoted elaboration of aziridines

被引：30

作者：

Mordini, A ^{[1
]}

Russo, F ^{[1
]}

Valacchi, M ^{[1
]}

Zani, L ^{[1
]}

Degl'Innocenti, A ^{[1
]}

Reginato, G ^{[1
]}

机构：

[1] Dipartimento Chim Organ U Schiff, Ist Chim Composti Organomet, I-50019 Florence, Italy

来源：

TETRAHEDRON | 2002年 / 58卷 / 35期

关键词：

aziridines; superbase; rearrangement; allyl amine; amino acid;

D O I：

10.1016/S0040-4020(02)00729-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The base-promoted isomerization of aziridines to allyl amines is still an almost unknown reaction. However, the use of superbasic reagents has shown to be able to promote a regio- and stereoselective conversion of monocyclic and bicyclic sulfonyl aziridines. Moreover, the use of alkoxy substituted aziridines opens new routes to non-natural alpha- and beta-amino acids. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：7153 / 7163

页数：11

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