Novel hybrid materials of magnetic nanoparticles and cellulose fibers

被引:81
作者
Small, Aaron C. [1 ,2 ]
Johnston, James H. [1 ,2 ]
机构
[1] Victoria Univ Wellington, Sch Chem & Phys Sci, Wellington, New Zealand
[2] MacDiarmid Inst Adv Mat & Nanotechnol, Wellington, New Zealand
关键词
Cellulose; Magnetic nanoparticles; IN-SITU SYNTHESIS; PAPER; FERRITES;
D O I
10.1016/j.jcis.2008.11.038
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, magnetic cellulose fibers have been prepared by coating bleached Kraft fibers (Pinus radiata) with magnetite nanoparticles. In doing so, the inherent properties of the fiber (such as tensile strength and flexibility) have been preserved, but imparted to it are the magnetic properties of the coating. The surface coating approach used differs from other methods in the literature in which the lumen loading or in si. tu approach is taken. After successive washings and sonication, the particles remained bonded to the surface of the fiber, and the fibers Could be formed into a paper sheet. The chemical and physical characterization of these materials were carried out using scanning electron microscopy (SEM), electron dispersive spectroscopy (EDS), X-ray fluorescence spectroscopy (XRF), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and SQUID magnetometry. SEM shows the Surface of the fibers to be completely encapsulated by the ferrite nanoparticles. This is also confirmed by EDS. XRD line broadening analysis shows the average particle sizes of the nanoparticles range from 1226 nm. Magnetically responsive cellulose fibers such as those synthesized in this study, will allow the investigation of new concepts in papermaking and packaging, security paper, and information storage. Potential applications are in electromagnetic shielding, magnetographic printing and magnetic filtering. (C) 2008 Elsevier Inc. All rights reserved.
引用
收藏
页码:122 / 126
页数:5
相关论文
共 12 条
[1]  
[Anonymous], [No title captured]
[2]  
[Anonymous], 1992, HDB XRAY PHOTOELECTR
[3]   Preparation and properties of an aqueous ferrofluid [J].
Berger, P ;
Adelman, NB ;
Beckman, KJ ;
Campbell, DJ ;
Ellis, AB ;
Lisensky, GC .
JOURNAL OF CHEMICAL EDUCATION, 1999, 76 (07) :943-948
[4]   FERRIMAGNETIC PAPER OBTAINED BY IN-SITU SYNTHESIS OF SUBSTITUTED FERRITES [J].
CARRAZANAGARCIA, JA ;
LOPEZQUINTELA, MA ;
REY, JR .
IEEE TRANSACTIONS ON MAGNETICS, 1995, 31 (06) :3126-3130
[5]   Characterization of ferrite particles synthesized in presence of cellulose fibers [J].
CarrazanaGarcia, JA ;
LopezQuintela, MA ;
RivasRey, J .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1997, 121 (01) :61-66
[6]   MAGNETIC CELLULOSE FIBERS AND PAPER - PREPARATION, PROCESSING AND PROPERTIES [J].
MARCHESSAULT, RH ;
RIOUX, P ;
RAYMOND, L .
POLYMER, 1992, 33 (19) :4024-4028
[7]  
MIDDLETON SR, 1989, J PULP PAP SCI, V15, pJ229
[8]   IN-SITU SYNTHESIS OF FERRITES IN CELLULOSICS [J].
RAYMOND, L ;
REVOL, JF ;
RYAN, DH ;
MARCHESSAULT, RH .
CHEMISTRY OF MATERIALS, 1994, 6 (02) :249-255
[9]   Electronic properties of intrinsically conducting polymer-cellulose based composites [J].
Richardson, MJ ;
Johnston, JH ;
Borrmann, T .
CURRENT APPLIED PHYSICS, 2006, 6 (03) :462-465
[10]   Properties of magnetite nanoparticles synthesized through a novel chemical route [J].
Thapa, D ;
Palkar, VR ;
Kurup, MB ;
Malik, SK .
MATERIALS LETTERS, 2004, 58 (21) :2692-2694