Glycosaminoglycan-mimetic biomaterials. 1. Nonsulfated and sulfated glycopolymers by cyanoxyl-mediated free-radical polymerization

被引：66

作者：

Grande, D

Baskaran, S

Baskaran, C

Gnanou, Y

Chaikof, EL ^{[1
]}

机构：

[1] Emory Univ, Sch Med, Lab Biomol Mat Res, Dept Surg, Atlanta, GA 30322 USA

[2] Emory Univ, Sch Med, Lab Biomol Mat Res, Dept Bioengn, Atlanta, GA 30322 USA

[3] Georgia Inst Technol, Sch Chem Engn, Atlanta, GA 30320 USA

[4] Univ Bordeaux 1, UMR ENSCPB, CNRS, Lab Chim Polymeres Organ, F-33402 Talence, France

来源：

MACROMOLECULES | 2000年 / 33卷 / 04期

关键词：

D O I：

10.1021/ma991579s

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A series of N-acetyl-D-glucosamine-containing glycomonomers was synthesized as an initial step in the synthesis of glycosaminoglycanmimetic glycopolymers. It was shown that cyanoxyl-mediated free-radical polymerization is an original and straightforward approach for obtaining water-soluble glycopolymers with high monosaccharide contents and low polydispersity indexes.

引用

页码：1123 / 1125

页数：3

共 19 条

[1] LIVING RADICAL POLYMERIZATION INVOLVING OXYGEN-CENTERED SPECIES ATTACHED TO PROPAGATING CHAIN ENDS [J].