The mid-IR absorption spectrum of gas-phase clusters of the nucleobases guanine and cytosine

被引：66

作者：

Bakker, JM

Compagnon, I

Meijer, G

von Helden, G

Kabelác, M

Hobza, P

de Vries, MS

机构：

[1] FOM, Inst Plasma Phys Rijnhuizen, NL-3439 MN Nieuwegein, Netherlands

[2] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany

[3] Acad Sci Czech Republ, Inst Organ Chem & Biochem, Prague 16610 6, Czech Republic

[4] Ctr Complex Mol Syst & Biomol, Prague 16610 6, Czech Republic

[5] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2004年 / 6卷 / 10期

关键词：

D O I：

10.1039/b316158g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The mid-infrared (IR) absorption spectrum of jet-cooled clusters of the nucleobases guanine and cytosine has been recorded in the 500-1800 cm(-1) range by ion-dip spectroscopy. Some 30 clearly separated and sharp resonances are observed. The combination of the experimental data with new high-level ab initio calculations is consistent with a previous structural assignment and a tentative assignment is made to the K7-1E structure of guanine-cytosine. These data can serve as a test of the method in the mid-IR regime.

引用

页码：2810 / 2815

页数：6

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