Two-dimensional correlation analysis

被引:71
作者
Harrington, PD [1 ]
Urbas, A [1 ]
Tandler, PJ [1 ]
机构
[1] Ohio Univ, Clippinger Labs, Dept Chem & Biochem, Ctr Intelligent Chem Instrumentat, Athens, OH 45701 USA
关键词
2D correlation analysis; multivariate data; cross-correlation;
D O I
10.1016/S0169-7439(99)00062-3
中图分类号
TP [自动化技术、计算机技术];
学科分类号
0812 ;
摘要
This tutorial reviews the recent computational advances in two-dimensional (2D) correlation spectroscopy, presents the theory, and provides examples applying 2D correlation analysis. Two-dimensional correlation analysis is a method for visualizing the relationships among the variables in multivariate data and their temporal behavior by applying the complex cross-correlation function. This function measures correlations that occur at the same rate or frequency with respect to the data acquisition time. The complex cross-correlation function yields real and imaginary components that contain information about the phase behavior of the variables. The real component provides information about mutually dependent in-phase variations. Variations that occur out-of-phase (with time lags or leads) are given by the imaginary component. Two-dimensional correlation analysis is a general analysis method that can be used for the treatment of data from a variety of applications including image, distribution, environmental, and kinetic analysis. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:149 / 174
页数:26
相关论文
共 20 条
[1]   Simplified and efficient method of computing generalized two-dimensional correlation spectra [J].
Burie, JR .
APPLIED SPECTROSCOPY, 1996, 50 (07) :861-865
[2]   Two-dimensional Fourier compression [J].
Cai, CS ;
Harrington, PD ;
Davis, DM .
ANALYTICAL CHEMISTRY, 1997, 69 (20) :4249-4255
[3]   Interpretation of two-dimensional correlation spectra: Science or art? [J].
Czarnecki, MA .
APPLIED SPECTROSCOPY, 1998, 52 (12) :1583-1590
[4]   NANOSECOND 2-DIMENSIONAL RESONANCE RAMAN CORRELATION SPECTROSCOPY OF BENZIL RADICAL-ANION [J].
EBIHARA, K ;
TAKAHASHI, H ;
NODA, I .
APPLIED SPECTROSCOPY, 1993, 47 (09) :1343-1344
[5]   QUANTITATIVE 2-DIMENSIONAL INFRARED (2D IR) SPECTROSCOPY - THEORETICAL DEVELOPMENT FOR GENERAL AND SPECIFIC CASES [J].
EKGASIT, S ;
ISHIDA, H .
APPLIED SPECTROSCOPY, 1995, 49 (09) :1243-1253
[6]  
GENG L, 1997 PITTSB C ATL GA
[7]  
MAGTOTO NP, IN PRESS APPL SPECTR
[8]   DYNAMIC 2-DIMENSIONAL IR SPECTROSCOPY [J].
MARCOTT, C ;
DOWREY, AE ;
NODA, I .
ANALYTICAL CHEMISTRY, 1994, 66 (21) :A1065-A1075
[9]   Two-dimensional FT-IR spectroscopy: A powerful method to study the secondary structure of proteins using H-D exchange [J].
Nabet, A ;
Pezolet, M .
APPLIED SPECTROSCOPY, 1997, 51 (04) :466-469
[10]   GENERALIZED 2-DIMENSIONAL CORRELATION METHOD APPLICABLE TO INFRARED, RAMAN, AND OTHER TYPES OF SPECTROSCOPY [J].
NODA, I .
APPLIED SPECTROSCOPY, 1993, 47 (09) :1329-1336