Tetrakis(tri-p-tolylphosphine-κP)silver(I) hexafluorophosphate

被引：9

作者：

Venter, Gertruida J. S. ^{[1
]}

Meijboom, Reinout ^{[1
]}

Roodt, Andreas ^{[1
]}

机构：

[1] Univ Orange Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷

关键词：

D O I：

10.1107/S160053680604760X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Ag(P(p-tol)(3)}(4)]PF6 or [Ag(C21H21P)(4)]-PF6, crystallizes with parts of two independent formula units in the asymmetric unit. The Ag-P distances range between 2.5665 ( 13) and 2.6142 ( 7) A, and the P-Ag-P angles between 109.310 ( 18) and 109.632 (18)degrees, indicating a distorted tetrahedral geometry. Both Ag atoms and both PF6- anions lie on threefold rotation axes.

引用

页码：M3453 / M3455

页数：3

共 15 条

[1] SIR97:: a new tool for crystal structure determination and refinement [J].

Altomare, A ;

Burla, MC ;

Camalli, M ;

Cascarano, GL ;

Giacovazzo, C ;

Guagliardi, A ;

Moliterni, AGG ;

Polidori, G ;

Spagna, R .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :115-119

[2]

[Anonymous], 2015, Acta Crystallogr., V71, P3

[3]

[Anonymous], 2005, APEX2 VERS 1 0 27

[4] LEWIS BASE ADDUCTS OF GROUP-11 METAL-COMPOUNDS .24. COORDINATION OF TRIPHENYLPHOSPHINE WITH SILVER-NITRATE - A SOLID-STATE CROSS-POLARIZATION MAGIC INFRARED SPECTROSCOPIC STUDY OF AG(PPH3)NNO3(N=1-4) [J].

BARRON, PF ;

DYASON, JC ;

HEALY, PC ;

ENGELHARDT, LM ;

SKELTON, BW ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (09) :1965-1970

[5] LEWIS-BASE ADDUCTS OF GROUP-11 METAL(I) COMPOUNDS .59. CRYSTAL-STRUCTURE DETERMINATIONS OF TETRAKIS(TRIMETHYLPHOSPHINE)COPPER(I) HALIDES AND TETRAKIS(TRIPHENYLPHOSPHINE)-COPPER(I) AND TETRAKIS(TRIPHENYLPHOSPHINE)-SILVER(I) HEXAFLUOROPHOSPHATES [J].

BOWMAKER, GA ;

HEALY, PC ;

ENGELHARDT, LM ;

KILDEA, JD ;

SKELTON, BW ;

WHITE, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1990, 43 (10) :1697-1705

[6]

BRANDENBURG K, 2005, DIAMOND RELEASE 3 0

[7]

*BRUK AXS INC, 2004, SAITN PLUS VERS 7 12

[8] STRUCTURE OF [AG(PPH3)4]PF6 [J].

COTTON, FA ;

LUCK, RL .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 :1222-1224

[9] LEWIS-BASE ADDUCTS OF GROUP-1B METAL(I) COMPOUNDS .13. CRYSTAL-STRUCTURE DETERMINATIONS OF TETRAKIS(TRIPHENYLPHOSPHINE)-COPPER(I) AND TETRAKIS(TRIPHENYLPHOSPHINE)-SILVER(I) PERCHLORATES, BIS(PYRIDINE)BIS(TRIPHENYL-PHOSPHINE)COPPER(I) PERCHLORATE, (2,2'-BIPYRIDYL)BIS(TRIPHENYL-PHOSPHINE)COPPER(I) PERCHLORATE, AND TETRAHYDROBORATOBIS-(TRIPHENYLPHOSPHINE)COPPER(I) PYRIDINE (1/0.5)E [J].

ENGELHARDT, LM ;

PAKAWATCHAI, C ;

WHITE, AH ;

HEALY, PC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (01) :125-133

[10]

Farrugia L. J., 1999, J. Appl. Crystallogr, V32, P837, DOI DOI 10.1107/S0021889899006020

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